Substitution reactions in the secondary ion mass spectrometry of  N ‐methylpyridinium halides | Zendy

Yoneda Michiaki | Zendy; Tanizaki Ken | Zendy; Tsujimoto Kazuo | Zendy; Ohashi Mamoru | Zendy

AI Assistant Blog Pricing

Home ZAIA Blog

Premium

Substitution reactions in the secondary ion mass spectrometry of N ‐methylpyridinium halides

Author(s) -

Yoneda Michiaki,

Tanizaki Ken,

Tsujimoto Kazuo,

Ohashi Mamoru

Publication year - 1993

Publication title -

organic mass spectrometry

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.475

H-Index - 121

eISSN - 1096-9888

pISSN - 0030-493X

DOI - 10.1002/oms.1210280607

Subject(s) - chemistry , ion , halide , halogen , mass spectrometry , pyridinium , mass spectrum , cluster (spacecraft) , deuterium , medicinal chemistry , inorganic chemistry , analytical chemistry (journal) , organic chemistry , alkyl , atomic physics , physics , chromatography , computer science , programming language

Secondary ion mass spectra of N ‐methylpyridinium halides (C + X − , where C + is a pyridinium cation and X − is a halogen anion) exhibit the C + ions, a series of cluster ions ((C + ) n (X − ) n –1 ) and, furthermore, remarkable [CX – R] + ions (R = H or Me). The mechanism of the formation of [CX – R] + ions was investigated by the use of deuterated compounds and B/E and B 2 / E constant linked‐scan measurements. A possible explanation is proposed in which the ions are produced through substitution reactions between species constituting the C 2 X + cluster ions in the gas phase.

This content is not available in your region!

Continue researching here.

Having issues? You can contact us here

Accelerating Research