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Tandem mass spectrometry of aminated fullerene derivatives
Author(s) -
Davey Simon N.,
Tetler Lee W.,
Leigh David A.,
Moody Andrew E.
Publication year - 1993
Publication title -
organic mass spectrometry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.475
H-Index - 121
eISSN - 1096-9888
pISSN - 0030-493X
DOI - 10.1002/oms.1210280515
Subject(s) - dimethylamine , chemistry , fragmentation (computing) , mass spectrometry , tandem mass spectrometry , mass spectrum , tandem , fullerene , fast atom bombardment , selected reaction monitoring , analytical chemistry (journal) , organic chemistry , chromatography , materials science , computer science , composite material , operating system
The products of the reaction between fullerenes (C 60 /C 70 ) and dimethylamine were investigated by fast atom bombardment (FAB) mass spectrometry and tandem mass spectrometry (MS/MS). The FAB mass spectrum shows peaks corresponding to the addition of up to eight dimethylamine species, exclusively to C 70 . MS/MS reveals an unusual fragmentation pattern. The mass spectrum of the reaction products, together with a number of tandem mass spectra, are shown.