Origin of the [M − H] +  ion in flavanone | Zendy

Guidugli Federico H. | Zendy; Kakva Juan | Zendy; Santillan Rosa L. | Zendy; Garibay Maria E. | Zendy; JosephNathan Pedro | Zendy

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Origin of the [M − H] + ion in flavanone

Author(s) -

Guidugli Federico H.,

Kakva Juan,

Santillan Rosa L.,

Garibay Maria E.,

JosephNathan Pedro

Publication year - 1992

Publication title -

organic mass spectrometry

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.475

H-Index - 121

eISSN - 1096-9888

pISSN - 0030-493X

DOI - 10.1002/oms.1210271125

Subject(s) - fragmentation (computing) , flavanone , ketene , chemistry , ion , labelling , metastability , deuterium , stereochemistry , biology , medicinal chemistry , physics , organic chemistry , biochemistry , ecology , atomic physics , flavonoid , antioxidant

Studies of the genesis of the [M − H] + ion in flavanone and 2′‐hydroxychalcone, performed with the aid of metastable decompositions and deuterium labelling, allow new structural notations to be postulated for the [M − H]+ ions, which in turn provide evidence for the pathways in the [M − H – ketene]+ fragmentation routes for these compounds.

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