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Study of the reactions and reaction mechanisms of phosphine (Ph 3 P) and of phosphite ((PhO) 3 P) with sulphur (S 8 )
Author(s) -
Zhang Haiying,
Peng Jiarou,
Peng Shiqi,
Wu Guowang,
Dai Duenhua,
Zhu Guozheng
Publication year - 1992
Publication title -
organic mass spectrometry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.475
H-Index - 121
eISSN - 1096-9888
pISSN - 0030-493X
DOI - 10.1002/oms.1210270113
Subject(s) - phosphine , mass spectrometry , fast atom bombardment , chemistry , reaction mechanism , sulfur , mechanism (biology) , photochemistry , medicinal chemistry , organic chemistry , catalysis , chromatography , philosophy , epistemology
The reactions of sulphur with phosphine and phosphite were investigated by low‐energy electron impact mass spectrometry and fast atom bombardment mass spectrometry. A previously reported mechanism of the Ph 3 P–S 8 reaction was supported and a possible mechanism for the (PhO) 3 P–S 8 reaction is proposed.