Methylcyclopropane ion formation by elimination of water from  n ‐butanol and 2‐methylpropanol ions | Zendy

Ahmed Mohammed S. | Zendy; Hudson Charles E. | Zendy; Giam C. S. | Zendy; McAdoo David J. | Zendy

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Methylcyclopropane ion formation by elimination of water from n ‐butanol and 2‐methylpropanol ions

Author(s) -

Ahmed Mohammed S.,

Hudson Charles E.,

Giam C. S.,

McAdoo David J.

Publication year - 1991

Publication title -

organic mass spectrometry

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.475

H-Index - 121

eISSN - 1096-9888

pISSN - 0030-493X

DOI - 10.1002/oms.1210261211

Subject(s) - ion , chemistry , ionization , mass spectrometry , hydrogen , ring (chemistry) , ion source , analytical chemistry (journal) , organic chemistry , chromatography

C 4 H 8 + ˙ ions generated from ionized n ‐butanol ( a ) and from ionized 2‐methylpropanol ( b ) were characterized by reaction of the daughter ions with ammonia in a Fourier transform mass spectrometer. Hydrogen transfers occur in a in the ratio five‐membered ring:six‐membered ring = 1:3.2. However, both hydrogen‐transfers are followed by the formation of ionized methylcyclopropane. Ionized methylcyclopropane is also produced on elimination of water from b .

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