Loss of CO from the molecular ions of  o ‐,  m ‐ and  p ‐anisoyl fluorides, CH 3 OC 6 H 4 COF, with fluorine atom migration | Zendy

Tajima Susumu | Zendy; Tobita Seiji | Zendy; Mitani Motohiro | Zendy; Akuzawa Kazuko | Zendy; Sawada Hideo | Zendy; Nakayama Masaharu | Zendy

Premium

Loss of CO from the molecular ions of o ‐, m ‐ and p ‐anisoyl fluorides, CH 3 OC 6 H 4 COF, with fluorine atom migration

Author(s) -

Tajima Susumu,

Tobita Seiji,

Mitani Motohiro,

Akuzawa Kazuko,

Sawada Hideo,

Nakayama Masaharu

Publication year - 1991

Publication title -

organic mass spectrometry

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.475

H-Index - 121

eISSN - 1096-9888

pISSN - 0030-493X

DOI - 10.1002/oms.1210261122

Subject(s) - fluorine , benzene , chemistry , fluoride , ion , ring (chemistry) , atom (system on chip) , medicinal chemistry , polyatomic ion , mass spectrometry , inorganic chemistry , crystallography , organic chemistry , chromatography , computer science , embedded system

Loss of CO from the molecular ions ([CH 3 OC 6 H 4 COF] + ˙) of o ‐, m ‐ and p ‐anisoyl fluorides has been investigated by mass‐analysed ion kinetic energy (MIKE) spectrometry. This reaction involves fluorine atom migration from the carbonyl group to the benzene ring. In the cases of o ‐ and p ‐anisoyl fluorides, the fluorine atom migrates via a three‐membered transition state to form the molecular ions ([CH 3 OC 6 H 4 F] + ˙) of o ‐ and p ‐fluoroanisoles, respectively. On the other hand, in the case of m ‐anisoyl fluoride, the fluorine atom migrates from the carbonyl group to the benzene ring via a three‐ or four‐membered transition state.

This content is not available in your region!

Continue researching here.

Having issues? You can contact us here

Accelerating Research