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Experiments on the formation of acylium ions from alkenic compounds following chemical ionization with no +
Author(s) -
Schneider B.,
Budzikiewicz H.
Publication year - 1991
Publication title -
organic mass spectrometry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.475
H-Index - 121
eISSN - 1096-9888
pISSN - 0030-493X
DOI - 10.1002/oms.1210260523
Subject(s) - ion , ionization , yield (engineering) , chemistry , cleavage (geology) , bond cleavage , computational chemistry , materials science , physics , organic chemistry , thermodynamics , fracture (geology) , composite material , catalysis
Alkenic compounds when subjected to chemical ionization with NO + yield two acylium ions by oxidative cleavage of the double bond. Studies on the mechanism of formation of these ions are reported.