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Azinyl sulphides. Part X. Mass spectrometry of some 3‐ and 4‐quinolinyl sulphides and 3,4‐quinolinediyl bis‐sulphides
Author(s) -
Pluta Krystian,
Maślankiewicz Andrzej
Publication year - 1990
Publication title -
organic mass spectrometry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.475
H-Index - 121
eISSN - 1096-9888
pISSN - 0030-493X
DOI - 10.1002/oms.1210250309
Subject(s) - chemistry , ion , mass spectrometry , radical , mass spectrum , analytical chemistry (journal) , organic chemistry , chromatography
The mass spectral fragmentations of ten of the title compounds are discussed. All the 3,4‐quinolinediyl bis‐sulphides give characteristic ions at m/z 159 and 132 while 3‐ and 4‐quinolinyl sulphides form ions at m/z 160 and 133. The most characteristic distinction between 3‐ and 4‐quinolinyl sulphides is the intensity of the [M ‐ 1] + ion. The elimination of · SH and · CH 3 radicals is also different.