Premium
Fragmentation of 1‐aryl‐5‐(2‐dialkylaminovinyl)‐1 H ‐tetrazoles upon electron impact
Author(s) -
Herrmann Michael,
Fischer Gerhard W.
Publication year - 1989
Publication title -
organic mass spectrometry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.475
H-Index - 121
eISSN - 1096-9888
pISSN - 0030-493X
DOI - 10.1002/oms.1210240917
Subject(s) - fragmentation (computing) , aryl , tetrazole , carbodiimide , chemistry , medicinal chemistry , electron ionization , ion , electron , stereochemistry , polymer chemistry , organic chemistry , physics , nuclear physics , computer science , alkyl , ionization , operating system
The mass spectrometric behaviour of 1‐aryl‐5‐(2‐dialkylaminovinyI)‐l H ‐tetrazoles was studied, especially 1‐phenyl‐5‐(2‐dimethylaminovinyl)‐l H ‐tetrazole as a typical example of D‐ and 15 N‐labelled derivatives revealed a rearrangement via a carbodiimide‐like intermediate ion.