Mass spectral fragmentation pathways in reduction metabolites of 2,4‐dinitrotoluene and 2,4,6‐trinitrotoluene. A tandem mass spectrometric collision induced dissociation study | Zendy

Yi Jehuda | Zendy

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Mass spectral fragmentation pathways in reduction metabolites of 2,4‐dinitrotoluene and 2,4,6‐trinitrotoluene. A tandem mass spectrometric collision induced dissociation study

Author(s) -

Yi Jehuda

Publication year - 1988

Publication title -

organic mass spectrometry

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.475

H-Index - 121

eISSN - 1096-9888

pISSN - 0030-493X

DOI - 10.1002/oms.1210230410

Subject(s) - fragmentation (computing) , chemistry , collision induced dissociation , tandem mass spectrometry , dissociation (chemistry) , tandem , electron ionization , mass spectrometry , analytical chemistry (journal) , chromatography , organic chemistry , ion , materials science , ionization , computer science , composite material , operating system

A collision induced dissociation study of a series of reduction metabolites of 2,4‐dinitrotoluene and 2,4,6‐trinitrotoluene was carried out using a tandem BB mass spectrometer. Fragmentation pathways of the metabolites were determined in the electron impact mode. It was found that the dominant fragmentation pathway is loss of OH ˙ due to an ortho effect. Other fragmentation routes include loss of NO 2 ˙ and loss of CH 2 N˙.

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