A mass spectrometric study of the dimethyl ester trimethylsilyl enol ether derivatives of some 3‐oxodicarboxylic acids | Zendy

Svendsen John S. | Zendy; Whist Jon E. | Zendy; Sydnest Leiv K. | Zendy

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A mass spectrometric study of the dimethyl ester trimethylsilyl enol ether derivatives of some 3‐oxodicarboxylic acids

Author(s) -

Svendsen John S.,

Whist Jon E.,

Sydnest Leiv K.

Publication year - 1987

Publication title -

organic mass spectrometry

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.475

H-Index - 121

eISSN - 1096-9888

pISSN - 0030-493X

DOI - 10.1002/oms.1210220803

Subject(s) - trimethylsilyl , fragmentation (computing) , chemistry , enol , decomposition , ether , dimethyl ether , enol ether , organic chemistry , medicinal chemistry , stereochemistry , catalysis , computer science , operating system

The fragmentation pathways for the dimethyl ester trimethylsilyl enol ether derivatives of some 3‐oxodicarboxylic acids have been found by using B/E and B 2 /E linked scans, collisional activated decomposition and isotope substitution techniques. The trimethylsilyloxy group strongly directs the decomposition processes, and induces a fragmentation pattern that intimately reflects the structure of the compounds.

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