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Mass spectrometric investigation of benzyliderieaniline
Author(s) -
Srzić Dunja,
Čevizović Nada,
Meić Zlatko
Publication year - 1987
Publication title -
organic mass spectrometry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.475
H-Index - 121
eISSN - 1096-9888
pISSN - 0030-493X
DOI - 10.1002/oms.1210220704
Subject(s) - fragmentation (computing) , chemistry , deuterium , fission , scrambling , ion , mass spectrum , electron ionization , labelling , hydrogen , photochemistry , organic chemistry , nuclear physics , physics , philosophy , neutron , ionization , operating system , linguistics , biochemistry , computer science
The mass spectral fragmentation of benzylideneaniline has been studied by deuterium labelling. Under electron impact, molecular ions undergo simple fission at the phenyl–N, phenyl–C and CN bonds, hydrogen migration reactions, and skeletal rearrangement fragmentations. Except in the skeletal rearrangement reactions, hydrogen scrambling does not feature in benzylideneaniline upon electron impact.