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Ion chemistry of α‐diazoketones. 1. A collissional activation study of 1‐diazo‐3‐phenoxypropan‐2‐one upon elecgtron impact
Author(s) -
Selva Antonio,
Ferrario Francesco,
Saba Antonio
Publication year - 1987
Publication title -
organic mass spectrometry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.475
H-Index - 121
eISSN - 1096-9888
pISSN - 0030-493X
DOI - 10.1002/oms.1210220403
Subject(s) - diazo , chemistry , ion , medicinal chemistry , organic chemistry
The gaseous ionic products of 1‐diazo‐3‐phenoxypropan‐2‐one upon electron impact show that cyclization reactions, which have counterparts in condensed‐phase chemistry, occur in competition with a mass spectral Wolff type rearrangement.