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Carbanion rearrangements: Collisionally activated dissociations of deprotonated alkyl malonates
Author(s) -
Hayes Roger N.,
Bowie John H.
Publication year - 1986
Publication title -
organic mass spectrometry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.475
H-Index - 121
eISSN - 1096-9888
pISSN - 0030-493X
DOI - 10.1002/oms.1210210709
Subject(s) - carbanion , chemistry , deprotonation , deuterium , fragmentation (computing) , malonate , alkyl , labelling , medicinal chemistry , mass spectrum , diethyl malonate , photochemistry , organic chemistry , ion , nuclear physics , physics , biochemistry , computer science , catalysis , operating system
The major fragmentations observed in the collisionally activated mass spectra of secondary and tertiary carbanions from malonate esters are quite different. For example, the major fragmentation by deuterium labelling where appropriate.