Mass spectra and stereochemistry of alkylsubstituted 2,2‐diphenyl‐1,3‐dioxa‐2‐germacyclohexanes | Zendy

Gren A. I. | Zendy; Yasinenko N. E. | Zendy; Timofeev O. S. | Zendy; Zagorevskii D. V. | Zendy

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Mass spectra and stereochemistry of alkylsubstituted 2,2‐diphenyl‐1,3‐dioxa‐2‐germacyclohexanes

Author(s) -

Gren A. I.,

Yasinenko N. E.,

Timofeev O. S.,

Zagorevskii D. V.

Publication year - 1986

Publication title -

organic mass spectrometry

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.475

H-Index - 121

eISSN - 1096-9888

pISSN - 0030-493X

DOI - 10.1002/oms.1210210702

Subject(s) - ring (chemistry) , benzene , chemistry , alkyl , mass spectrum , stereoselectivity , stereochemistry , hydrogen atom , electron ionization , spectral line , medicinal chemistry , crystallography , physics , organic chemistry , ion , catalysis , ionization , astronomy

The correlations between electron impact induced formation of fragment [M C 6 H 6 ] + ˙ from alkyl‐substituted 2,2‐diphenyl‐1,3‐dioxa‐2‐germacyclohexane (1) and the peculiarities of the molecular structures were found. Benzene elimination is regiospecific and stereoselective, resulting from the abstraction of an axial phenyl group and a hydrogen atom from the C‐4 or C‐6 position of the ring.

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