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Fragmentation of the chain in the mass spectra of the pyrrolidides of alkylcyclohexanecarboxylic acids
Author(s) -
Vetter W.,
Meister W.
Publication year - 1986
Publication title -
organic mass spectrometry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.475
H-Index - 121
eISSN - 1096-9888
pISSN - 0030-493X
DOI - 10.1002/oms.1210210208
Subject(s) - steric effects , fragmentation (computing) , mass spectrum , chemistry , chain (unit) , spectral line , computational chemistry , stereochemistry , crystallography , mass spectrometry , physics , biology , chromatography , ecology , astronomy
The electron impact mass spectra of the pyrrolidides of both the cis‐ and trans‐ octylcyclohexanecarboxylic acids show the structure of the aliphatic chain, despite the steric hindrance of a direct H transfer from the chain to the functional group.
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