Secondary isotope effect on kinetic energy release and reaction symmetry | Zendy

Hvistendahl Georg | Zendy; Uggerud Einar | Zendy

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Secondary isotope effect on kinetic energy release and reaction symmetry

Author(s) -

Hvistendahl Georg,

Uggerud Einar

Publication year - 1985

Publication title -

organic mass spectrometry

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.475

H-Index - 121

eISSN - 1096-9888

pISSN - 0030-493X

DOI - 10.1002/oms.1210200902

Subject(s) - protonation , kinetic isotope effect , deuterium , kinetic energy , formaldehyde , chemistry , hydrogen atom , carbon atom , hydrogen , isotope , photochemistry , carbon fibers , isotopes of carbon , radiochemistry , computational chemistry , materials science , organic chemistry , atomic physics , physics , nuclear physics , ion , ring (chemistry) , alkyl , quantum mechanics , composite number , composite material , total organic carbon

A secondary deuterium isotope effect on the kinetic energy release has been observed for the loss of molecular hydrogen from protonated formaldehyde and protonated methylimine. The results have been used to show that the centre of the reactions lies towards the carbon atom.

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