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Stereospecific hydride transfer under NCI/OH − conditions. 2—Origins of the C 2 H 4 O elimination from stereoisomeric alkoxyketal derivatives 1
Author(s) -
Tabet JeanClaude,
Hanna Issam,
Fetizon Marcel
Publication year - 1985
Publication title -
organic mass spectrometry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.475
H-Index - 121
eISSN - 1096-9888
pISSN - 0030-493X
DOI - 10.1002/oms.1210200114
Subject(s) - stereospecificity , chemistry , alkoxide , intramolecular force , hydride , decomposition , spectral line , medicinal chemistry , stereochemistry , catalysis , organic chemistry , hydrogen , physics , astronomy
A new stereospecific intramolecular hydride transfer, induced by an alkoxide, has been demonstrated under NCI/OH − conditions using unimolecular and collision‐induced decomposition spectra.