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A mass spectrometric study of the adducts of acetylacetone and cyanogen (Traube's isomers)
Author(s) -
Basato M.,
Corain B.,
Veronese A. C.,
Daolio S.,
Pelli B.,
Traldi P.
Publication year - 1985
Publication title -
organic mass spectrometry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.475
H-Index - 121
eISSN - 1096-9888
pISSN - 0030-493X
DOI - 10.1002/oms.1210200111
Subject(s) - chemistry , adduct , acetylacetone , mass spectrometry , derivative (finance) , decomposition , deuterium , cyanogen , labelling , analytical chemistry (journal) , organic chemistry , chromatography , biochemistry , physics , financial economics , economics , quantum mechanics
The mass spectrometric behaviour of the title compounds has been studied in detail with the aid of deuterium labelling, exact mass measurements, linked scans and collisionally activated decomposition experiments. An interesting conversion reaction of the cyanoenaminedione isomer into the corresponding furane derivative, which appears complete in the second field free region, has been thoroughly investigated.