Fragmentation of selected C 6 H 10 O isomers: Evidence for a common [C 5 H 7 O] +  ion generated by methyl loss from cyclohexene oxide and 5,6‐dihydro‐4‐methyl‐2 H ‐pyran | Zendy

Alai Mehrshid | Zendy; Rye Robin T. B. | Zendy

Premium

Fragmentation of selected C 6 H 10 O isomers: Evidence for a common [C 5 H 7 O] + ion generated by methyl loss from cyclohexene oxide and 5,6‐dihydro‐4‐methyl‐2 H ‐pyran

Author(s) -

Alai Mehrshid,

Rye Robin T. B.

Publication year - 1984

Publication title -

organic mass spectrometry

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.475

H-Index - 121

eISSN - 1096-9888

pISSN - 0030-493X

DOI - 10.1002/oms.1210191009

Subject(s) - fragmentation (computing) , ion , metastability , mass spectrum , dissociation (chemistry) , chemistry , spectral line , analytical chemistry (journal) , kinetic energy , collision induced dissociation , oxide , mass spectrometry , crystallography , physics , tandem mass spectrometry , organic chemistry , astronomy , chromatography , quantum mechanics , computer science , operating system

The loss of CH 3 ˙ from the molecular ions of cyclohexene oxide and 5,6‐dihydro‐4‐methyl‐2 H ‐pyran has been investigated. On the basis of metastable peak shape analysis, collision‐induced dissociation/mass‐analysed ion kinetic energy spectra and thermochemical data it is concluded that the same [C 5 H 7 O] + ion is formed in both cases.

This content is not available in your region!

Continue researching here.

Having issues? You can contact us here

Accelerating Research