Premium
The isomerization mechanism of alkylamines: Structure of [C 2 H 6 N] + and [C 3 H 8 N] + fragment ions
Author(s) -
Audier H. E.,
Milliet A.,
Sozzi G.,
Denhez J. P.
Publication year - 1984
Publication title -
organic mass spectrometry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.475
H-Index - 121
eISSN - 1096-9888
pISSN - 0030-493X
DOI - 10.1002/oms.1210190206
Subject(s) - isomerization , ion , fragmentation (computing) , spectral line , crystallography , chemistry , stereochemistry , physics , catalysis , operating system , biochemistry , organic chemistry , astronomy , computer science
The MIKE spectra of amines RCH 2 NH 2 containing more than five carbon atoms exhibit m / z 44 and m / z 58 peaks. The structures of these [C 2 H 6 N] + and [C 3 H 8 N] + ions have been established by collisional activation spectra. The results are in agreement with the fragmentation mechanisms previously proposed.