The structures of [C 5 H 5 O] +  ions formed from isomers of nitrophenol in the gaseous phase | Zendy

Porter C. J. | Zendy; Proctor C. J. | Zendy; Larka E. A. | Zendy; Bey J. H. | Zendy

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The structures of [C 5 H 5 O] + ions formed from isomers of nitrophenol in the gaseous phase

Author(s) -

Porter C. J.,

Proctor C. J.,

Larka E. A.,

Bey J. H.

Publication year - 1982

Publication title -

organic mass spectrometry

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.475

H-Index - 121

eISSN - 1096-9888

pISSN - 0030-493X

DOI - 10.1002/oms.1210170709

Subject(s) - ion , metastability , fragmentation (computing) , chemistry , analytical chemistry (journal) , crystallography , materials science , organic chemistry , computer science , operating system

Translational energy release measurments on metastable ions are used in the comparison of the structures of isomeric ions. Metastable ions, m 2 + , formed from m 1 + ions as the result of a high energy process in the ion source are compared with isomeric metastable ions formed as daughters from fragmentation of metastable m 1 + ions in a field. In the case of o ‐, m ‐ and p ‐nitrophenol the structure of the [C 5 H 5 O] + ions formed from [C 6 H 5 O] + ions by these two independent methods is different as verified by comparison of the behaviour of [C 5 H 5 O] + ions formed from several other compounds.

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