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The chemical ionization mass spectra of 2,4‐adamantanediol diacetates and dimethyl ethers
Author(s) -
D'Haenens L.,
Van de Sande C. C.,
Schelfaut M.
Publication year - 1982
Publication title -
organic mass spectrometry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.475
H-Index - 121
eISSN - 1096-9888
pISSN - 0030-493X
DOI - 10.1002/oms.1210170605
Subject(s) - isobutane , chemistry , mass spectrum , chemical ionization , methane , reagent , ionization , organic chemistry , spectral line , analytical chemistry (journal) , catalysis , ion , physics , astronomy
The chemical ionization mass spectra of the isomeric 2,4‐adamantanediol diacetates and dimethyl ethers have been determined using methane and isobutane as reagent gases. The significant differences in the spectra of the diacetates allow an unambiguous identification of the isomers. The spectra of the trideuteroacetates reveal the occurrence of protolysis in the ionizing plasma.