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The fragmentation behavior of the endo ‐ and exo ‐octahydro‐4,7‐methano‐1 H ‐indene systems
Author(s) -
Inman Roger C.,
Servé M. Paul
Publication year - 1982
Publication title -
organic mass spectrometry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.475
H-Index - 121
eISSN - 1096-9888
pISSN - 0030-493X
DOI - 10.1002/oms.1210170505
Subject(s) - fragmentation (computing) , indene , chemistry , deuterium , molecule , stereochemistry , labelling , computational chemistry , medicinal chemistry , organic chemistry , physics , biology , biochemistry , nuclear physics , ecology
The electron impact induced fragmentations of the endo ‐ and exo ‐octahydro‐4,7‐methano‐1 H ‐indene systems have been studied. The principal decomposition reactions have been elucidated by deuterium labelling. Two generic fragmentation patterns appeared: one involved the bisection of the molecule and the second involved the loss of various alkyl fragments.