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Flowing afterglow studies of the reactions between negative ions and trimethylsilyl enol ethers. Regiospecific generation of gas phase enolate ions
Author(s) -
Squires Robert R.,
Depuy Charles H.
Publication year - 1982
Publication title -
organic mass spectrometry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.475
H-Index - 121
eISSN - 1096-9888
pISSN - 0030-493X
DOI - 10.1002/oms.1210170407
Subject(s) - enol , chemistry , afterglow , ion , trimethylsilyl , hydroxide , silylation , photochemistry , ionic bonding , amide , inorganic chemistry , medicinal chemistry , organic chemistry , catalysis , physics , gamma ray burst , astronomy
Reactions of isomeric silyl enol ethers with fiuoride, amide or hydroxide ions in a flowing afterglow lead to the formation of relatively pure isomeric enolate anions. Isomeric enolates react specifically with neopentyl nitrite to give ionic products diagnostic of their structure.