The structures and formation of [C 4 H 6 N] +  ions 2—ion structures derived from 2‐methylpropanenitrile | Zendy

Sarneel Maria M. | Zendy; Heerma Wigger | Zendy; Dijkstra Geo | Zendy

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The structures and formation of [C 4 H 6 N] + ions 2—ion structures derived from 2‐methylpropanenitrile

Author(s) -

Sarneel Maria M.,

Heerma Wigger,

Dijkstra Geo

Publication year - 1982

Publication title -

organic mass spectrometry

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.475

H-Index - 121

eISSN - 1096-9888

pISSN - 0030-493X

DOI - 10.1002/oms.1210170402

Subject(s) - ion , fragmentation (computing) , mass spectrum , electron ionization , deuterium , ionization , metastability , spectral line , molecule , chemistry , hydrogen , stripping (fiber) , hydrogen atom , atomic physics , materials science , physics , alkyl , organic chemistry , astronomy , computer science , operating system , composite material

The loss of a hydrogen atom from ionized 2‐methylpropanenitrile is preceded by a drastic rearrangement of the molecular ion. The result of this fragmentation is the generation of two stable structurally different [C 4 H 6 N] + ions, formed via different pathways. Their structures can be established by a careful comparison of the metastable ion spectra, collision activation spectra, and charge stripping spectra from the compound and its three deuterium labeled analogues and from [C 4 H 6 N] + ions generated from reference compounds via electron impact ionization or in selected ion/molecule reactions.

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