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Electron impact mass spectrometry of 3‐cyclohexen‐1‐ol and related compounds
Author(s) -
Braem Daniel,
Siles Samuel,
Gülaçar Fazil O.,
Buchs Armand
Publication year - 1982
Publication title -
organic mass spectrometry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.475
H-Index - 121
eISSN - 1096-9888
pISSN - 0030-493X
DOI - 10.1002/oms.1210170210
Subject(s) - deuterium , electron ionization , mass spectrometry , double bond , chemistry , mass spectrum , medicinal chemistry , electron , photochemistry , organic chemistry , computational chemistry , chromatography , physics , ion , nuclear physics , ionization
The electron impact mass spectrum of 3‐cyclohexen‐1‐ol has been studied, especially with regard to the retro Diels‐Alder reaction. Six deuterium labelled analogues and two dimethyl substituted homologues were synthesized. Contrary to what we have observed with 2‐cyclohexen‐1‐ol, the double bond migration which precedes the retro Diels‐Alder reaction plays a minor role.