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Some stereochemical effects in gaseous ion decompositions
Author(s) -
Reddy A. Mahender,
Nayar M. S. B.,
Reddy G. Sudhakar,
Das K. G.
Publication year - 1982
Publication title -
organic mass spectrometry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.475
H-Index - 121
eISSN - 1096-9888
pISSN - 0030-493X
DOI - 10.1002/oms.1210170107
Subject(s) - isobutane , chemical ionization , ion , ionization , chemistry , electron ionization , ammonia , methane , photochemistry , inorganic chemistry , organic chemistry , catalysis
Stereochemical effects were observed in the electron ionization, methane, isobutane and ammonia positive ion chemical ionization and hydroxy negative ion chemical ionization behaviour of some isomeric triaryl nitrocyclohexenes. cis ‐Eliminations leading to loss of HNO 2 , H 2 NO 2 and arene were found to be stereochemically preferred in gaseous ions.