Unimolecular ethyl loss from metastable  13 C labelled [C 5 H 10 O] +˙  ions with the oxygen on the middle carbon: An example for incomplete energy randomization? | Zendy

Depke Gisbert | Zendy; Schwarz Helmut | Zendy

Premium

Unimolecular ethyl loss from metastable 13 C labelled [C 5 H 10 O] +˙ ions with the oxygen on the middle carbon: An example for incomplete energy randomization?

Author(s) -

Depke Gisbert,

Schwarz Helmut

Publication year - 1981

Publication title -

organic mass spectrometry

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.475

H-Index - 121

eISSN - 1096-9888

pISSN - 0030-493X

DOI - 10.1002/oms.1210160913

Subject(s) - radical , isomerization , chemistry , enol , carbon fibers , oxygen , ion , photochemistry , medicinal chemistry , organic chemistry , materials science , catalysis , composite number , composite material

The investigation of 13 C labelled 3‐pentanone cation radicals generated via isomerization of the corresponding [C 5 H 10 O] +˙ enol cation radicals demonstrates unambiguously that, in contrast to previous investigations, unimolecular ethyl loss from 13 C labelled 3‐pentanone cation radicals is preceded by complete energy randomization.

This content is not available in your region!

Continue researching here.

Having issues? You can contact us here

Accelerating Research