Stable adduct formation during the gas phase reactions between the trimethylgermanium cation and organic nucleophiles. An ion cyclotron resonance study | Zendy

Trenerry V. Craige | Zendy; Bowie John H. | Zendy

Premium

Stable adduct formation during the gas phase reactions between the trimethylgermanium cation and organic nucleophiles. An ion cyclotron resonance study

Author(s) -

Trenerry V. Craige,

Bowie John H.

Publication year - 1981

Publication title -

organic mass spectrometry

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.475

H-Index - 121

eISSN - 1096-9888

pISSN - 0030-493X

DOI - 10.1002/oms.1210160805

Subject(s) - adduct , chemistry , nucleophile , mass spectrometry , trimethylsilyl , ion cyclotron resonance , reagent , ion , fourier transform ion cyclotron resonance , gas phase , ionization , chemical ionization , resonance (particle physics) , phase (matter) , inorganic chemistry , medicinal chemistry , organic chemistry , cyclotron , chromatography , catalysis , physics , particle physics

The trimethylgermanium cation (Me 3 Ge + ) reacts with aliphatic organic neutrals (M) which contain N, O or S, to form adducts [M + Me 3 Ge + ] in the gas phase. These adducts are more stable than their analogues formed from the trimethylsilyl cation, and thus Me 3 Ge + is a useful analytical reagent for chemical ionization mass spectrometry.

This content is not available in your region!

Continue researching here.

Having issues? You can contact us here

Accelerating Research