Four isomers of [C 3 H 8 O] +˙  distinguished by collisional activation | Zendy

Crow Frank W. | Zendy; Gross Michael L. | Zendy; Bursey Maurice M. | Zendy

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Four isomers of [C 3 H 8 O] +˙ distinguished by collisional activation

Author(s) -

Crow Frank W.,

Gross Michael L.,

Bursey Maurice M.

Publication year - 1981

Publication title -

organic mass spectrometry

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.475

H-Index - 121

eISSN - 1096-9888

pISSN - 0030-493X

DOI - 10.1002/oms.1210160709

Subject(s) - dimethoxyethane , chemistry , ether , bicyclic molecule , ion , propanol , spectral line , medicinal chemistry , stereochemistry , organic chemistry , methanol , physics , astronomy , electrode , electrolyte

Collisional activation of the molecular ions of 1‐propanol, 2‐propanol and methyl ethyl ether, and of the m / z 60 ion from 1,2‐dimethoxyethane provides evidence for four distinct forms of [C 3 H 8 O] +˙ . Collision induced decompositions may be explained either by simple cleavages, by cyclic processes involving adjacent substituents, or by bicyclic processes of adjacent substituents. Evidence for a form of [C 3 H 8 O] +˙ in which charge and radical site are separate is assembled from the spectra.

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