Isomers of the molecular ion of 2,3‐diphenyl‐1,4‐benzodioxin. A comparative study with the different isomeric molecular ions of benzocyclobutenyl derivatives of 1,4‐benzodioxin | Zendy

Dagaut Jacques | Zendy; Fillaux Joëlle | Zendy; Leblanc Danielle | Zendy; Dizabo Pierre | Zendy

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Isomers of the molecular ion of 2,3‐diphenyl‐1,4‐benzodioxin. A comparative study with the different isomeric molecular ions of benzocyclobutenyl derivatives of 1,4‐benzodioxin

Author(s) -

Dagaut Jacques,

Fillaux Joëlle,

Leblanc Danielle,

Dizabo Pierre

Publication year - 1980

Publication title -

organic mass spectrometry

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.475

H-Index - 121

eISSN - 1096-9888

pISSN - 0030-493X

DOI - 10.1002/oms.1210150505

Subject(s) - isomerization , ion , deuterium , chemistry , radical , polyatomic ion , computational chemistry , organic chemistry , physics , nuclear physics , catalysis

From a study of the elimination of carbonylated radicals from 2,3‐diphenyl‐1,4‐benzodioxin and certain specifically deuterated derivatives, it has been possible to calculate the relative abundances of the different isomeric molecular ions formed. A comparison with phenylbenzocyclobutenyl derivatives of 1,4‐benzodioxin indicates that the isomerization schemes are similar.

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