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Mass spectrometric studies of 2‐nitrosophenols
Author(s) -
Charalambous J.,
Fysh R. R.,
Herbert C. G.,
Johri M. H.,
Shutie W. M.
Publication year - 1980
Publication title -
organic mass spectrometry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.475
H-Index - 121
eISSN - 1096-9888
pISSN - 0030-493X
DOI - 10.1002/oms.1210150502
Subject(s) - tautomer , isomerization , fragmentation (computing) , enthalpy , mass spectrum , chemistry , mass spectrometry , ion , computational chemistry , analytical chemistry (journal) , photochemistry , organic chemistry , chromatography , thermodynamics , physics , catalysis , computer science , operating system
The mass spectra of 2‐nitrosophenols are independent of the insertion temperature, suggesting that the compounds either do not exhibit tautomerism in the vapour phase or that the enthalpy of isomerization is low. However, their fragmentation patterns suggest tautomerism in the molecular ion.