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Flophemesyl derivatives of alcohols, phenols, amines and carboxylic acids: Derivatives for mass spectrometric ion monitoring and structure determination
Author(s) -
Francis Ainsley J.,
Morgan E. D.,
Poole C. F.
Publication year - 1978
Publication title -
organic mass spectrometry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.475
H-Index - 121
eISSN - 1096-9888
pISSN - 0030-493X
DOI - 10.1002/oms.1210131111
Subject(s) - chemistry , phenols , ion , carboxylic acid , mass spectrum , organic chemistry , mass spectrometry , selected ion monitoring , chromatography , gas chromatography–mass spectrometry
The flophemesyl (or pentafluorophenyldimethylsilyl) derivatives of representative alcohols, phenols, carboxylic acids and amines show rather simple spectra with a few abundant ions at high mass, characteristic of the parent compound and a few ions at low mass characteristic of the flophemesyl group. These derivatives are useful in the structure determination of simple compounds, and for the determination by single or multiple ion monitoring of known compounds at low levels.