The time dependence of the competing processes leading to the loss of C 2 H 4  from tetralin | Zendy

Levsen K. | Zendy; Borchers F. | Zendy; Stolze R. | Zendy; Budzikiewicz H. | Zendy

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The time dependence of the competing processes leading to the loss of C 2 H 4 from tetralin

Author(s) -

Levsen K.,

Borchers F.,

Stolze R.,

Budzikiewicz H.

Publication year - 1978

Publication title -

organic mass spectrometry

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.475

H-Index - 121

eISSN - 1096-9888

pISSN - 0030-493X

DOI - 10.1002/oms.1210130906

Subject(s) - tetralin , scrambling , kinetic energy , ion , decomposition , ionization , chemistry , computational chemistry , photochemistry , analytical chemistry (journal) , organic chemistry , physics , solvent , computer science , algorithm , quantum mechanics

Field ionization kinetic measurements indicate that loss of C 2 H 4 from the molecular ion of tetralin occurs via competing processes, viz. (a) at short times the retro Diels‐Alder decomposition which is a high energy process, (b) loss from positions 1+2 (=3+4) and (c) loss after complete C and H scrambling which gains in importance for long ion lifetimes.

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