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The dependence of the extent of C 2 H 6 elimination on the orientation of the C 2 H 5 group in ethylbicyclo [4.4.0]decanes
Author(s) -
Zaikin V. G.,
Smetanin V. I.,
Musaev I. A.,
Kurashova E. Kh.
Publication year - 1978
Publication title -
organic mass spectrometry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.475
H-Index - 121
eISSN - 1096-9888
pISSN - 0030-493X
DOI - 10.1002/oms.1210130613
Subject(s) - orientation (vector space) , group (periodic table) , epimer , ion , chemistry , crystallography , stereochemistry , mathematics , geometry , organic chemistry
The elimination of C 2 H 6 from the molecular ions of trans ‐fused 2‐ and 3‐ethylbicyclo [4.4.0] decanes with the axial C 2 H 5 group takes place to a greater extent than in the corresponding equatorial epimers.
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