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Elimination reactions of ions in the gas phase. V —elimination of water in hydroxybornanes and related compounds
Author(s) -
Robbiani R.,
Bührer H.,
Mändli H.,
Kovačević D.,
Fraefel A.,
Seibl J.
Publication year - 1978
Publication title -
organic mass spectrometry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.475
H-Index - 121
eISSN - 1096-9888
pISSN - 0030-493X
DOI - 10.1002/oms.1210130509
Subject(s) - borneol , deuterium , stereospecificity , chemistry , ion , elimination reaction , ring (chemistry) , cleavage (geology) , labelling , gas phase , medicinal chemistry , radiochemistry , stereochemistry , organic chemistry , materials science , catalysis , nuclear physics , biochemistry , physics , composite material , medicine , alternative medicine , pathology , traditional chinese medicine , fracture (geology)
Results of an investigation of deuterium labelled methylated norborneols and dihydrocarveols are presented to show that the 1,2 elimination of water in borneol and isoborneol is triggered by an initial ring cleavage reaction. Other eliminations of water in borneol and isoborneol are elucidated by specific and stereospecific deuterium labelling in different positions.