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On the fragmentation of stereoisomeric substituted cyclohexylamines under electron impact. Comparison with corresponding alcohols and ethers
Author(s) -
Weissdorf Miriam,
Sharvit Joseph,
Mandelbaum Asher
Publication year - 1978
Publication title -
organic mass spectrometry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.475
H-Index - 121
eISSN - 1096-9888
pISSN - 0030-493X
DOI - 10.1002/oms.1210130307
Subject(s) - stereospecificity , cyclohexanol , chemistry , fragmentation (computing) , cleavage (geology) , electron ionization , ring (chemistry) , medicinal chemistry , stereochemistry , organic chemistry , catalysis , ion , materials science , biology , fracture (geology) , composite material , ionization , ecology
The stereospecific elimination of H 2 O and CH 3 OH from substituted cyclohexanols and their methyl ethers upon electron impact is not reproduced in the corresponding amines. Ring cleavage α to the amino group is responsible for the non‐stereospecific formation of the most abundant fragments in the amines.