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A study of deuterium exchange in adamantane carboxylic acids and alcohols under electron impact
Author(s) -
Yurchenko A. G.,
Dovgan N. L.,
Chizhov O. S.,
Karpenko N. F.,
Ya. Podel'ko A.
Publication year - 1977
Publication title -
organic mass spectrometry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.475
H-Index - 121
eISSN - 1096-9888
pISSN - 0030-493X
DOI - 10.1002/oms.1210120210
Subject(s) - adamantane , deuterium , chemistry , carboxylic acid , hydrogen–deuterium exchange , medicinal chemistry , organic chemistry , hydrogen , physics , nuclear physics
Abstract The mass spectra of 1‐adamantyl substituted carboxylic acids and alcohols with and without deuterated hydroxyl groups were studied. Deuterium exchange between functional group and adamantane nucleus was observed and a possible explantation of the phenomenon is given.