Mass spectrometric studies of 6‐chloro‐6 H ‐dibenz[ c , e ] [1,2]oxaphosphorine‐6‐sulphide and its derivatives | Zendy

Bhatia M. S. | Zendy

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Mass spectrometric studies of 6‐chloro‐6 H ‐dibenz[ c , e ] [1,2]oxaphosphorine‐6‐sulphide and its derivatives

Author(s) -

Bhatia M. S.

Publication year - 1977

Publication title -

organic mass spectrometry

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.475

H-Index - 121

eISSN - 1096-9888

pISSN - 0030-493X

DOI - 10.1002/oms.1210120103

Subject(s) - chemistry , alkoxy group , medicinal chemistry , fragmentation (computing) , derivative (finance) , stereochemistry , organic chemistry , alkyl , computer science , financial economics , economics , operating system

The electron‐impact induced fragmentation of 6‐chloro‐6 H ‐dibenz[ c , e ] [1,2]oxaphosphorine‐6‐sulphide and its 6‐ethoxy and 6‐hydroxy derivatives has been studied and it has been found that formation of the dibenz[ c , e ] [1,2]oxaphosphorin system and elimination of HCP are common features. β‐Hydrogen rearrangement, in the case of the ethoxy derivative, is comparable to ethers with a POCH 2 CH 3 linkage.

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