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The electron impact‐induced fragmentation of perchlorylbenzene
Author(s) -
Giumanini Angelo G.,
Lunelli Bruno
Publication year - 1976
Publication title -
organic mass spectrometry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.475
H-Index - 121
eISSN - 1096-9888
pISSN - 0030-493X
DOI - 10.1002/oms.1210110603
Subject(s) - fragmentation (computing) , electron ionization , ion , chlorine , electron , oxygen , chemistry , physics , organic chemistry , computer science , ionization , nuclear physics , operating system
The modes of fragmentation of perchlorylbenzene (C 6 H 5 ClO 3 ) and its perdeutero derivative under electron impact are reported and discussed. The occurrence of the [C 6 H 5 O] − and [C 6 H 5 O] + ions is accounted for in terms of a novel phenyl migration from chlorine to oxygen.
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