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Stepwise retro 1,3‐dipolar cycloaddition induced by electron. Impact on 3,5‐diphenyl‐1,2,4‐oxadiazole
Author(s) -
Selva Antonio,
Traldi Pietro,
Zerilli Luigi F.,
Gallo Gian Gualberto
Publication year - 1976
Publication title -
organic mass spectrometry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.475
H-Index - 121
eISSN - 1096-9888
pISSN - 0030-493X
DOI - 10.1002/oms.1210110219
Subject(s) - oxadiazole , cycloaddition , 1,3 dipolar cycloaddition , chemistry , dipole , electron , computational chemistry , organic chemistry , physics , catalysis , nuclear physics
The retro 1,3‐dipolar cycloaddition induced by electron impact on 3,5‐diphenyl‐1,2,4‐oxadiazole is interpreted as a two‐step process on the basis of the energetics and kinetics of the fragments [C 7 H 5 NO] + ., [C 6 H 5 CN] + . and [C 6 H 5 CO] + .