Mass spectrometry of heterocyclic compounds. X —The unusual cleavage of the alkyl–oxygen bond of 3‐carboxyesters of 2‐phenyl‐4‐pyridones | Zendy

Selva A. | Zendy; Gennaro A. | Zendy; Caramella P. | Zendy

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Mass spectrometry of heterocyclic compounds. X —The unusual cleavage of the alkyl–oxygen bond of 3‐carboxyesters of 2‐phenyl‐4‐pyridones

Author(s) -

Selva A.,

Gennaro A.,

Caramella P.

Publication year - 1976

Publication title -

organic mass spectrometry

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.475

H-Index - 121

eISSN - 1096-9888

pISSN - 0030-493X

DOI - 10.1002/oms.1210110204

Subject(s) - chemistry , alkyl , cleavage (geology) , mass spectrometry , bond cleavage , ion , medicinal chemistry , oxygen , electron ionization , oxygen atom , polymer chemistry , molecule , organic chemistry , catalysis , materials science , chromatography , fracture (geology) , composite material , ionization

The dominant and unusual electron impact‐induced losses of CH 3 ⋅ and C 2 H 5 ⋅ from molecular ions of 3‐carbomethoxy and 3‐carbethoxy derivatives of 2‐phenyl‐4‐pyridones are explained by invoking the participation of the phenyl group.

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