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Negative ions in organic mass spectrometry. II —Negative ion mass spectra of simple thio and dithio esters.
Author(s) -
Rullkötter Jürgen,
Budzikiewicz Herbert
Publication year - 1976
Publication title -
organic mass spectrometry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.475
H-Index - 121
eISSN - 1096-9888
pISSN - 0030-493X
DOI - 10.1002/oms.1210110107
Subject(s) - thio , fragmentation (computing) , mass spectrum , chemistry , ion , nitro , mass spectrometry , nitrite , medicinal chemistry , organic chemistry , chromatography , nitrate , alkyl , computer science , operating system
The 70 eV negative ion mass spectra of some simple aromatic and aliphatic thio and dithio esters are discussed. A characteristic fragmentation process, a rearrangement analogous to the nitro‐nitrite conversion of aromatic nitro compounds, is observed for aromatic thio esters.