The reactive states of ions: Octatrienes and dimethyl substituted cyclohexadienes | Zendy

Rennekamp M. E. | Zendy; Hoffman M. K. | Zendy

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The reactive states of ions: Octatrienes and dimethyl substituted cyclohexadienes

Author(s) -

Rennekamp M. E.,

Hoffman M. K.

Publication year - 1975

Publication title -

organic mass spectrometry

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.475

H-Index - 121

eISSN - 1096-9888

pISSN - 0030-493X

DOI - 10.1002/oms.1210101205

Subject(s) - excited state , ion , ground state , decomposition , molecule , radical , spectroscopy , cis–trans isomerism , chemistry , photochemistry , materials science , stereochemistry , organic chemistry , atomic physics , physics , quantum mechanics

The principal decomposition routes of molecular ions of cis , cis , cis ‐2,4,6‐octatriene, cis , cis , trans ‐2,4,6‐octatriene, trans , cis , trans ‐2,4,6‐octatriene, trans ‐5,6‐dimethyl‐1,3‐cyclohexadiene and cis ‐5,6‐dimethyl‐1,3‐cyclohexadiene were studied using ion kinetic spectroscopy. The loss of radicals from [M] + · appears to proceed via a ground state, while loss of a neutral molecule appears to involve either complete equilibration of structure within the system or both ground state and excited state pathways.

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