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Mass spectra of polymeric thioformaldehydes (CH 2 S) 3 , (CH 2 S) 4 , (CH 2 S) 5 and (CH 2 S) x
Author(s) -
Peach Michael E.,
Weissflog Eckhard,
Pelz Norbert
Publication year - 1975
Publication title -
organic mass spectrometry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.475
H-Index - 121
eISSN - 1096-9888
pISSN - 0030-493X
DOI - 10.1002/oms.1210100914
Subject(s) - mass spectrum , spectral line , fragmentation (computing) , chemistry , materials science , analytical chemistry (journal) , crystallography , physics , mass spectrometry , organic chemistry , chromatography , astronomy , computer science , operating system
The mass spectral fragmentations of various thioformaldehydes, 1,3,5‐trithiacyclohexane, 1,3,5,7‐tetrathiacyclooctane, 1,3,5,7,9‐pentathiacyclodecane and a polymeric form (CH 2 S) x have been examined. The principal features of the spectra are reported. The fragmentation occurred by fracture of the ring in the cyclic compounds with or without rearrangement.