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The high pressure nitric oxide mass spectra of aldehydes
Author(s) -
Jardine Ian,
Fenselau Catherine
Publication year - 1975
Publication title -
organic mass spectrometry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.475
H-Index - 121
eISSN - 1096-9888
pISSN - 0030-493X
DOI - 10.1002/oms.1210100909
Subject(s) - mass spectrum , chemistry , torr , nitric oxide , hydride , mass spectrometry , spectral line , ion , methane , oxide , analytical chemistry (journal) , chemical ionization , ionization , inorganic chemistry , hydrogen , organic chemistry , chromatography , physics , astronomy , thermodynamics
The high pressure (0.5 Torr) nitric oxide mass spectra of some aldehydes, obtained using a 10% mixture of NO in N 2 , are reported. The 10% NO/N 2 spectra of the monodeuterated analogs of some of them are compared to the electron‐impact and methane chemical ionization spectra, especially with reference to the process of hydride abstraction by nitrosonium ions.