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The mass spectrometric fragmentation of n‐benzylacetamide
Author(s) -
Gilbert J. R.,
Potter E.,
Stace A. J.
Publication year - 1975
Publication title -
organic mass spectrometry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.475
H-Index - 121
eISSN - 1096-9888
pISSN - 0030-493X
DOI - 10.1002/oms.1210100411
Subject(s) - acetanilide , fragmentation (computing) , mass spectrum , chemistry , polyatomic ion , dissociation (chemistry) , ion , hydrogen , collision induced dissociation , spectral line , analytical chemistry (journal) , mass spectrometry , photochemistry , organic chemistry , tandem mass spectrometry , chromatography , physics , astronomy , computer science , operating system
The low energy mass spectra of N ‐benzylacetamide have been recorded. The major fragmentations of the molecular ion are similar to those observed in the acetanilide spectrum. In addition, the secondary dissociation of the [C 6 H 5 CH 2 NH] + ion by loss of HCN is shown to occur with transfer of the ‐N–H hydrogen to the ring.