Isomerisation of hydrocarbon ions:II—Octenes and isomeric cycloakanes: Acollisional activation study | Zendy

Levsen K. | Zendy

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Isomerisation of hydrocarbon ions:II—Octenes and isomeric cycloakanes: Acollisional activation study

Author(s) -

Levsen K.

Publication year - 1975

Publication title -

organic mass spectrometry

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.475

H-Index - 121

eISSN - 1096-9888

pISSN - 0030-493X

DOI - 10.1002/oms.1210100109

Subject(s) - isomerization , ion , octene , hydrocarbon , chemistry , photochemistry , polyatomic ion , ethylene , stereochemistry , medicinal chemistry , organic chemistry , catalysis

[C 8 H 16 ] +. molecular ions from alkenes and cycloalkanes differing in their skeletal con‐figuration do not in general isomerise completely to a common structure, except for the molecular ion of n ‐propylcyclopentane, the structure of which is identical to that of the normal octene ions. In contrast, decomposing [C n H 2n−1 ] + fragments are completely or almost completely isomerised after a lifetime of a few μs.

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