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On the rearrangement and scrambling of hydrogen in the benzophenone oxime molecular ion
Author(s) -
Kramer V.,
Medved M.,
Kralj B.,
Marsel J.
Publication year - 1974
Publication title -
organic mass spectrometry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.475
H-Index - 121
eISSN - 1096-9888
pISSN - 0030-493X
DOI - 10.1002/oms.1210090905
Subject(s) - benzophenone , scrambling , oxime , chemistry , fragmentation (computing) , ion , photochemistry , radical , hydrogen , deuterium , medicinal chemistry , organic chemistry , physics , atomic physics , philosophy , linguistics , computer science , operating system
The losses of CO, hydrogen and CO, OH and HNOH radicals from the benzophenone oxime molecular ion have been studied by means of deuterium labelled compounds. Hydrogen scrambling and/or exchange and rearrangement reactions of interest, taking place prior to fragmentation, were observed.